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Mixed Metal Bis(m-oxo) Complexes with [CuM(m-O)2]2+ (M = Ni(III) or Pd(II)) Cores

Aboelella, N. W.; York, J. T.; Reynolds, A. M.; Fujita, K.; Kinsinger, C. R.; Cramer, C. J.; Riordan, C. G.; Tolman, W. B.
Chem. Commun. 2004, 1716.

Two highly reactive heterodinuclear bis(m-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at -80o C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

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